My favorite VNs would be Fate/Stay Night, G-Senjou no Maou and Muv Luv Alternative.
Fate/Stay Night is probably the VN with the most original plot i've ever seen. So original that it was worth an anime that became more famous than the VN itself. The best part about Fate/Stay Night (besides the masterly narrated history) is that it's 3 stories in one. You have 3 completely different plots each time you start the VN. I had an amazing time playing this ( and a loooooonnngg time trying to get all dojos ) It's fun, it's good and it has amazing endings, so this is probably my favorite VN of all time.
G-Senjou no Maou has the best plot i've ever seen in my life. I dare to say that i has one of the best plots of all time in any media. The story is geniusly narrated in ways that i cannot express in words. I almost went into a catatonic state everytime a twist happened in the story. And you know what, i played the VN LOOKING for then. I was aware at the time that it has lots of plo twists, but even so, i was baffled every time. Best story ever, i think it deserves my second place.
Muv Luv Alternative is the most well written VN that exists. I strongly recommend to those who didn't played it to play Extra and Unlimited first. Only the you can truly appreciate this magnificent masterpiece. It builds the foundation (in a boring slice of life story, i have to admit....) to become one Super Ultra Mecha Epic with lots of action, and thecnology, and feelings, and girls, and military, and quantum physics madness, and mental problems, and true love, and death, and lots of death, and aliens, and tons of death, and A PLOT TWIST THAT WILL BLOW YOUR F&*#ING MIND !!!!!
I'M SERIOUS, I STILL CAN'T SLEEP WELL !!!
I think that's my favorites.
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I used to do reviews on a blog. . . . . . . .