I appreciate you taking the time to try and point me in the right direction, however, none of the information was especially useful. I copied it to the root of my C drive just to try it out and the result was still the same. However I am noticing the trend of Windows 7 64bit causing errors, but seeing as others were able to get the game to start up, I'm not inclined to think that it is causing the issue. For the moment, at any rate. My problem for right now, is that neither of the exe files are able to start the program.
EDIT: I've also just tried out some compatibility settings, to no effect. I've also tried out the things listed in the "Before you Post" thread.